Monday, February 1, 2010

Kinetic Study of the Complexation of Palladium (II) with 2-(5-Bromo-2-Pyridylazo)-5-Diethylaminophenol

Kinetic Study of the Complexation of Palladium (II) with 2-(5-Bromo-2-Pyridylazo)-5-Diethylaminophenol

Bassem F. Shraydeh; Ali Z. Abu Zuhri

Chemistry Department, Faculty of Science, An-Najah National University, Nablus, West Bank
Received : 00-00-0000 , Accepted : 00-00-0000
Language: English

Abstract

The kinetics of the complexation reaction of palladium with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol (5-Br-PADAP) has been studied in the stability time at the optimum pH of 3.53 in presence of 50% ethanol. The effect of ionic strength and temperature on the reaction rate were reported. A mechanism has been postulated and the stability constants of the individual steps were determined. The Arrhenius and thermodynamic parameters were evaluated and discussed.


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