Monday, February 1, 2010

Short Communication: Addition of Bis (methylthio) acetylene to Nitrilium Salts

Short Communication: Addition of Bis (methylthio) acetylene to Nitrilium Salts

Rajab Abu El-Halawa, J.C. Jochims

1 Assistant Prof. Department of Chemistry, Faculty of Science, An-Najah National University; 2 Prof. Dr. Department of Chemistry, Konstanz University, West Germany
Received : 00-00-0000 , Accepted : 00-00-0000
Language: English
Abstract

Azaallenium salt 7 was isolated at low temperature by the addition of bis (methylthio) acetylene to nitrilium salts. The isolated azaallenium salt 7 was rearranged to afford the 1:1 heterocyclic adduct 8. A detailed mechanism is discussed.

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